Peeling is the spontaneous loss of ribbons or sheets of paint due to loss of adhesion. When the surface is coated with a primer and topcoat, or with several coats of paint, the peeling may involve all the coats, some of them, or just the topcoat.
Solution
If exterior moisture is the cause, eliminate the source by doing necessary repairs and maintenance:
If moist air is originating from inside, consider installing vents (especially in rooms that tend to get humid such as the kitchen, bathroom and laundry room); attic louvres, exhaust fans and dehumidifiers may also help. Remove all loose paint with a scraper or wire brush, sand rough surfaces and prime any bare wood. Repaint with an ultra premium quality acrylic paint - it will provide excellent adhesion and allow water vapour to escape without harming the coating.
This information is provided by the Rohm & Haas Paint Quality Institute, www.paintquality.com.au